Mineralogically investigated were massive sulfide samples of chimneys and mounds collected during the "SHINKAI 6500" dives (Dive 562 and Dive 567) from two basalt-hosted hydrothermal ore deposits, being at a short distance of about 1 km, occurring in the eastern end of the Yaeyama Central Graben, the Southern Okinawa Trough. In both sample series (#562-and #567-series), ore minerals are dominated by low-iron sphalerite with small amounts of chalcopyrite and galena. Sphalerite in the #567-series samples shows somewhat wide compositional variation, ranging from 0.4 to 3.8 mole%FeS, with the highest mode of about 1 to 2 mole%FeS. Significant amounts of pyrite and secondary marcasite are present in the #562-series samples with subordinate bornite, while in the #567-series samples, they are lacking, but instead tetrahedrite-tennantite series with atomic ratios of Sb/(Sb+As) being 0.2 to 0.8 is abundant and contains Ag up to 0.7wt% with mostly less than 0.5 wt%. Neither pyrrhotite nor isocubanite is encountered in the two sample series. Microthermometries of two-phase (liquid + gas) fluid inclusions trapped in calcite (#567-series) have revealed the following results: homogenization temperatures (not corrected for pressure) of 242 to 317 °C and salinities of 5.1 to 7.6 wt.%NaCl equiv., being a little more saline than the seawater. The observed mineral assemblages and sphalerite compositions obtained for the Yaeyama Central Graben deposits lead us to indicate that the basalt-hosted mineralizations might have occurred under rather higher sulfidation state. From the mineral associations observed, it is also indicated that both hydrothermal deposits are characterized by a metal association of essentially Zn-Pb-Cu. The mineral assemblages and ore textures observed are similar to those of the Kuroko deposits rather than the Besshi-type deposits, as well as their metal association (Cu-Pb-Zn).

Efficient regioselective synthesis of β-amino alcohol derivatives, including enantioenriched ones, by tetraarylphosphonium salt-catalyzed coupling reaction of epoxides with trichloroacetonitrile is described. Formal [3+2] cycloaddition followed by hydrolysis proceeded smoothly to...

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