A quantum‐mechanical model of charge condensation is proposed for non‐conjugated polar elastomers It was found that the stability of the bi‐ and multi‐polaron state may be achieved if the dielectrical permeability of the matrix is high enough. It is shown that the multi‐electron unit, called as superplaron, should have a linear structure and possess ferromagnetic properties. The one‐dimensional character of the conductivity of a superpolaron leads to the formation of electron pairs and to the appearance of high temperature superconductivity of superpolarons. A lot of experimental data confirms the real existance of superconductivity at some polar elastomers at 300 K.