The SnCl4 catalyzed glycosylation reaction of -peracetylated sugar derivative (glucose) with fatty alkanols is used in the synthesis of C7-C16-alkyl glucopyranosides.

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The SnCl4 catalyzed glycosylation reaction of peracetylated ?-D-derivatives with terminally unsaturated C3?C11 alkenols was used for the synthesis of some C3?C11 alkenyl ?-D-galactopyranosides, as precursors for unsaturated neutral bolaforms.

Carbohydrates Carbohydrates U 0500Synthesis of ω-Unsaturated O-Protected Glucosides as Precursors for Unsaturated Neutral Bolaforms. -Depending on the reaction time, βor α-anomers, e.g. (V) and (VII), resp., are formed. -(KONSTANTINOVIC*, S.; PREDOJEVIC, J.; GOJKOVIC, S.; PAVLOVIC, V.; Indian J.

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