Laboratory tests and physical-chemical modeling have determined that mixtures of activated silica and carbonatite, serpophite and carbonatite show considerable promise for developing artificial geochemical barriers. The obtained average contents of nickel and copper deposited on geochemical barriers in the formed mining induced ores are acceptable for their subsequent cost efficient processing using either pyro- or hydrometallurgy methods. Some tests of geochemical barriers have been carried out, involving the use of polluted water in the impact zone of the "Kol'skaya GMK" JSC. A possibility of water purification from heavy metals down to the MAC level for fishery water bodies has been displayed.

The speciation of chemical elements in groundwaters of Apatity Kirovsky district may affect their bioavailability and toxicity. A complete hydrochemical analysis showed measurable concentrations of uranium, molybdenum, silver, barium, nickel, vanadium, aluminum, and lead, which contributed to a growing database of the chemical compositions of groundwater. Physical and chemical models showed that the vital elements calcium, sodium, potassium, magnesium and sulfate ion are in chemical forms that are favorable for human health (Ca2+, Na+, K+, Mg2+, SO42-). Forms of migration of carcinogenic or toxic elements (nickel, barium, vanadium, strontium, aluminum, lead) are among the most toxic (Ni2+, Ba2+, Sr2+) and remain so at the temperatures studied +3, +25, +37°C. One of the most insidious effects of inorganic compounds of lead, barium and strontium is the ability to replace calcium in bones isomorphically, nickel in the form of free ions (Ni2+) is 2 times more toxic than its complex compounds with inorganic and organic ligands. The results of this research can be useful in the fields of geochemistry, hydrology, ecology and medicine.

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Processes of surface and underground water forming in the Khibiny massif have been studied using a physical-chemical model of the "water-rock-atmosphere-organic substance" system. The obtained model solutions are indicative of the fact that formation of surface and underground water of the Khibiny massif takes place on the whole in the framework of the considered system without attracting a hypothetical outside source of pollutants. The results are of practical and methodological importance for assessment of prediction of the man-induced impact on water systems in conditions of Subarctic.

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