Spirotetramat is a unique insecticide having both phloem and xylem mobility and imidacloprid, a neonicotinoid insecticide, is one of the most widely used in the world. The combination formulation is very effective against sucking pests of mango. Residue dynamics of spirotetramat and imidacloprid in/on mango and soil was studied following application of the combination formulation, spirotetramat 12% + imidacloprid 12% (240 SC) at 90 and 180 g a.i. ha(-1). Spirotetramat residues in/on mango fruits were 0.327 and 0.483 mg kg(-1) after giving 3 applications at 90 and 180 g a.i. ha(-1), respectively. The residues remained on mango fruits for 7 days and dissipated with the half-life of 3.3 and 5.2 days, respectively. Residues of spirotetramat-enol, the major metabolite of spirotetramat in plant, were not detected in mango fruits. Initial residues of imidacloprid on mango fruits from the two treatments were 0.329 and 0.536 mg kg(-1), respectively. Imidacloprid residues remained on mango fruits beyond 15 days and dissipated with the half-life of 5.2 and 8.2 days. The residues of spirotetramat, spirotetramat-enol and imidacloprid were found below quantifiable limit of 0.05 mg kg(-1) in mature mango fruits and field soil at harvest.

Multi-location supervised field trials were conducted in India at four locations of the All India Network Project (AINP) on Pesticide Residues to study the persistence, dissipation and risk assessment of flubendiamide and deltamethrin on cucumber (Cucumis sativus). Residues of flubendiamide and deltamethrin on cucumber resulting from three spray applications of a combination formulation (flubendiamide 90% + deltamethrin 60%, 150 SC) at recommended (22.5 + 15 g a.i./ha) and double the recommended (45 + 30 g a.i./ha) dose were analysed. On the basis of persistence and dissipation studies, the half- life (T) of flubendiamide on cucumber varied from 1.40 to 2.98 (recommended dose) and 1.55 to 2.76 days (double the recommended dose), while that of deltamethrin ranged from 2.5 to 4.9 (recommended dose) and 2.7 to 3.9 days (double the recommended dose) at the four locations. On the basis of supervised field trial data and using OECD calculator, MRLs in the combination product of 3 mg kg for flubendiamide and 1.5 mg kg for deltamethrin has been proposed for consideration by the Food Safety and Standards Authority of India (FSSAI). Codex, EU and EPA have fixed MRL of 0.2 mg kg for flubendiamide and deltamethrin.

Carbendazim is widely used on pomegranate for control of a large number of fungal diseases. Its residue levels in/on pomegranate fruits and soil were evaluated under field conditions. The quick, easy, cheap, effective, rugged, and safe (QuEChERS) method in conjunction with liquid-chromatography mass spectrometry was used for analysis of carbendazim. Recovery of carbendazim was within 78.92-96.28 % and relative standard deviation within 3.8-10.9 % (n = 6). Carbendazim residues on pomegranate fruits dissipated at the half lives of 17.3 and 22.8 days from treatments at 500 and 1000 g active ingredient (a.i.) ha(-1), respectively. Its residues in pomegranate aril were highest on the tenth day and reduced thereafter. The residue level of carbendazim on pomegranate whole fruits from standard dose treatment was less than the EU maximum residue limit (MRL) of 0.1 mg kg(-1) at harvest. The carbendazim residues were