The Duff formylation of 5 bromo or 5 chloro 8 hydroxyquinoline leads to the corresponding 7 formyl derivatives, condensation of which with 2 methyleneindolines or 3Н indolium halides in the presence of a base afforded new photochromic 6´ halo substituted spiro[indoline 2,2´ 2H pyrano[3,2 h]quinolines]. Thermal and photo induced isomerization of compounds obtained have been investigated by 1 Н NMR and UV spectroscopy.
Coordination chemistry Z 0150 Luminescent Complexes with Ligands Containing C=N Bond -[100 refs.]. -(METELITSA, A. V.; BURLOV, A. S.; BEZUGLYI, S. O.; BORODKINA, I. G.; BREN, V. A.; GARNOVSKII, A. D.; MINKIN, V. I.; Russ. J. Coord. Chem. (Transl. of Koord. Khim.) 32 (2006) 12, 858-868; Inst. Phys. Org. Chem., Rostov State Univ., Rostov-on-Don 344104, Russia; Eng.) -Lindner 51-229
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