No abstract

Preparation of the parent hydroxylamine of the title nitroxide and its conversion into several hydroxylamine derivatives and the corresponding nitroxides has been achieved with a view to using functionalised aryl nitroxides as spin labels. The aN values of the derived aryl nitroxides vary with the nature of their para-substituents, thus providing a potential method for identifying the site of attachment of aryl nitroxide spin labels.Reactions of a nitrone-nitroxide, derived from the title radical, with cyanoisopropyl, phenyl, benzoyloxyb and t-butoxyl radicals were investigated. In no case was a bisnitroxide formed. Bu t , N

No abstract

No abstract

2‐Methyl‐2‐nitrosopropane and its dimer product: 2‐methyl‐2‐nitropropane intermediate: N‐tert‐ Butylhydroxylamine intermediate: 2‐ Methyl ‐2‐ nitrosopropane