In the structure of bis(diethyldithiocarbamato

No abstract

The title compound, SeLBr [L-= diethyldithiocarbamate, (C,H,),NCS;] is the first example of Se(I1) complex featuring a dithiocarbamate and a halide. It was obtained by the reaction of Se(1V)bromide with tetraethylthiuram disulfide in a methanol solution containing hydrobromic acid. The structure determination of the compound shows it to be polymeric with bromine being the bridging ligand. The crystals of SeLBr are monoclinic with a = 10.391(3), b = 8.434(4), c = 12.030(2) A, p = 108.10(2)", V = 1002.15 p, Z = 4 and space group, P2,/n; R = 0.073, R , = 0.074.