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An experimental scheme ͑double pump/reflectivity probe using femtosecond laser pulses͒ enables the investigation of nonequilibrium electron dynamics at metal surfaces by measuring the equilibrated surface temperature. The competition between electron-phonon coupling and hot-electron transport gives rise to a reduced equilibrated temperature when the two pump pulses overlap in time, and provides a way of accurately determining the electron-phonon coupling constant. These observations have important consequences for femtosecond photochemical investigations.

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