We present the first results of our survey of asteroid polarization-phase curves in the near-infrared J and H bands using the WIRC+Pol instrument on the Palomar 200inch telescope. We confirm through observations of standard stars that WIRC+Pol can reach the 0.1% precision needed for asteroid phase curve characterization, and show that C-complex asteroids could act as an alternate calibration source as they show less wavelength variation than stellar polarized standards. Initial polarization-phase curve results for S-complex asteroids show a shift in behavior as a function of wavelength from visible to near-infrared bands, extending previously observed trends. Full nearinfrared polarization-phase curve characterization of individual asteroids will provide a unique constraint on surface composition of these objects by probing the wavelength dependence of albedo and index of refraction of the surface material.