A quantitative procedure for the hydrosilylation of allylic −SiMe3 protected phenols with
Et3SiH and Si−H terminated carbosilane dendrimers of first, second, and fourth generations
have been performed to give nG-[(CH2)3{C6H4
-
r
(OMe)
r
}OH]
m
. The subsequent treatment with
[Ti(C5Me5)Cl2Me], [Ti(C5Me5)Me3], or [M(C5H5)2ClX] (M = Ti, X = Cl; M = Zr, X = H) afforded
the corresponding organometallic metallodendrimers.
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