4-hydroxydithiocoumarin is a valuable organic precursor to architect important heterocycles. The three different reactive nucleophilic sites at the 4-hydroxydithiocoumarins display intriguing regioselectivity in its reaction towards various electro-philes. Previously, 4-hydroxydithiocoumarins...
A regioselective synthetic strategy for 6-aryl-8,9-dihydro-benzo[c]phenanthridine-10(7H)-ones (4) is accomplished using a one-pot four-component reaction by fine-tuning of reaction temperature. DMSO is excellently used as a reactant-cum-solvent to introduce carbonyl functionality...
The hitherto unreported 2-aryl-10H-thiochromeno[3,2-b][1,4]oxathiin-10-one derivatives are accomplished in a single pot from 4-hydroxydithiocoumarins, arylacetylenes and dimethyl sulfoxide in the presence of 10 mol% CuI and K2CO3 in an oil-bath at...
An unprecedented metal-free and catalyst-free synthesis of benzo[c]chromeno[4,3,2-gh]phenanthridine derivatives, a class of 1,6-diheterophenalenoid heterocycle, is reported for the first time. The oxidative cross-coupling reaction for the remote cyclization is achieved...
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