The age distribution of water in hydrologic systems has received renewed interest recently, especially in relation to watershed response to rainfall inputs. The purpose of this contribution is first to draw attention to existing theories of age distributions in population dynamics, fluid mechanics and stochastic groundwater, and in particular to the McKendrick-von Foerster equation and its generalizations and solutions. A second and more important goal is to clarify that, when hydrologic fluxes are modeled by means of time-varying stochastic processes, the age distributions must themselves be treated as random functions. Once their probabilistic structure is obtained, it can be used to characterize the variability of age distributions in real systems and thus help quantify the inherent uncertainty in the field determination of water age. We illustrate these concepts with reference to a stochastic storage model, which has been used as a minimalist model of soil moisture and streamflow dynamics.
Although the concepts of age, survival, and transit time have been widely used in many fields, including population dynamics, chemical engineering, and hydrology, a comprehensive mathematical framework is still missing. Here we discuss several relationships among these quantities by starting from the evolution equation for the joint distribution of age and survival, from which the equations for age and survival time readily follow. It also becomes apparent how the statistical dependence between age and survival is directly related to either the age dependence of the loss function or the survival‐time dependence of the input function. The solution of the joint distribution equation also allows us to obtain the relationships between the age at exit (or death) and the survival time at input (or birth), as well as to stress the symmetries of the various distributions under time reversal. The transit time is then obtained as a sum of the age and survival time, and its properties are discussed along with the general relationships between their mean values. The special case of steady state case is analyzed in detail. Some examples, inspired by hydrologic applications, are presented to illustrate the theory with the specific results.
Microbial growth is a clear example of organization and structure arising in nonequilibrium conditions. Due to the complexity of the microbial metabolic network, elucidating the fundamental principles governing microbial growth remains a challenge. Here, we present a systematic analysis of microbial growth thermodynamics, leveraging an extensive dataset on energy-limited monoculture growth. A consistent thermodynamic framework based on reaction stoichiometry allows us to quantify how much of the available energy microbes can efficiently convert into new biomass while dissipating the remaining energy into the environment and producing entropy. We show that dissipation mechanisms can be linked to the electron donor uptake rate, a fact leading to the central result that the thermodynamic efficiency is related to the electron donor uptake rate by the scaling law η∝μED−1/2 and to the growth yield by η∝Y4/5. These findings allow us to rederive the Pirt equation from a thermodynamic perspective, providing a means to compute its coefficients, as well as a deeper understanding of the relationship between growth rate and yield. Our results provide rather general insights into the relation between mass and energy conversion in microbial growth with potentially wide application, especially in ecology and biotechnology.
Background: Heavy-ion induced two-nucleon transfer reactions are powerful tools to reveal peculiar aspects of the atomic nucleus, such as pairing correlations, single-particle and collective degrees of freedom, and more. Also, these processes are in competition with the direct meson exchange in the double charge exchange reactions, which have recently attracted great interest due to their possible connection to neutrinoless double-β decay. In this framework, the exploration of two-nucleon transfer reactions in the 20 Ne + 116 Cd collision at energies above the Coulomb barrier is particularly relevant since the 116 Cd nucleus is a candidate for the double-β decay.Purpose: We want to analyze selected transitions to low-lying 0 + and 2 + states of the residual nuclei in the 116 Cd( 20 Ne, 22 Ne) 114 Cd two-neutron pickup and 116 Cd( 20 Ne, 18 O) 118 Sn two-proton stripping reactions at 306 MeV incident energy and determine the role of the couplings with inelastic transitions. Methods: We measured the excitation energy spectra and absolute cross sections for the two reactions using the MAGNEX large acceptance magnetic spectrometer to detect the ejectiles. We performed direct coupled reaction channels and sequential distorted wave Born approximation calculations using the double folding São Paulo potential to model the initial and final state interactions. The spectroscopic amplitudes for two-and singleparticle transitions were derived by different nuclear structure approaches: microscopic large-scale shell model, interacting boson model-2 and quasiparticle random phase approximation. Results:The calculations are able to reproduce the experimental cross sections for both two-neutron and twoproton transfer reactions. The role of couplings with the inelastic channels are found to be important in the two-proton transfer case. A competition between the direct and the sequential process is found in the reaction *
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