SYNOPSISCoir fibers were chemically modified through alkali treatment, and crosslinking with formaldehyde, para-phenylene diamine, phthalic anhydride, and combined crosslinking-cyanoethylation reactions in appropriate solvent and catalyst. The parent and chemically modified coir were characterized by FTIR spectra. The percent moisture regain, tensile strength, and behavior toward some chemical reagents (solubility %) of parent and chemically modified fibers have also been evaluated. The modified fibers showed significant hydrophobicity, improved tensile strength, and good chemical resistance. 0 1995
ABSTRACT:In this article, we report the transesterification of coir with n-Butyl acrylate (BA) and methyl acrylate (MA) under appropriate reaction conditions using NaOH and/or pyridine (Py) as catalyst. The modified vinylog coir was subsequently cured with benzoylperoxide (BPO) in acetone at 50-60ЊC. The modified fibers were characterized by Fourier transform infrared (FTIR) spectroscopy. Transesterification and curing of transesterified coir lowered the percentage of moisture regain and imparted improved tensile strength and resistance to common chemical reagents.
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