A new approach based on the Reproducing Kernel Hilbert Space Method is proposed to approximate the solution of the second-kind nonlinear integral equations. In this case, the Gram-Schmidt process is substituted by another process so that a satisfactory result is obtained. In this method, the solution is expressed in the form of a series. Furthermore, the convergence of the proposed technique is proved. In order to illustrate the effectiveness and efficiency of the method, four sample integral equations arising in electromagnetics are solved via the given algorithm.