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The effect of (Pt-loaded)TiO2 crystallite diameter (i.e. Scherrer size) on the photocatalytic water splitting rate was investigated. (Pt-loaded)TiO2 powders with a wide range of crystallite diameters from about 16 to 45 nm with a blank region between about 23 and 41 nm were prepared by various annealing processes from an identical TiO2 powder. Water splitting experiments with these powders were carried out with methanol as an oxidizing sacrificial agent. It was found that the photocatalytic water splitting rate was sensitively affected by the crystallite diameter of the (Pt-loaded)TiO2 powder. More concretely, similar steep improvements of photocatalytic water splitting rates from around 15 and a little over 2 to about 30 μmol•m −2 •hr −1 were obtained in the two (Pt-loaded)TiO2 crystallite diameters ranging from 16 to 23 and from 41 to 45 nm, respectively.

A pulsating fluidized bed is operated with two sequential durations designated as an on-period with injecting fluidization gas and an off-period without it. The heat transfer coefficient between a vertically immersed heater and bed in a pulsating fluidized bed is measured under various pulse cycles and fluidized particles. The obtained results are compared with those in a normal fluidized bed with continuous fluidization air injection. The relationship between heat transfer coefficients and bubble characteristics, evaluated using a digital video camera, has also been investigated. For certain fluidized particles and operating pulse cycles, the fluidization of particles and the increment of heat transfer coefficients can be obtained under a mean air velocity based on a pulse cycle duration smaller than the minimum fluidization air velocity in a normal fluidized bed. Under the pulse cycles where a static bed through the whole bed is formed in the off-period duration, the improved heat transfer rate over that in a normal fluidized bed can be measured. This may be attributed to large bubble formation. As heat transfer in the pulsating fluidized bed is obstructed with increasing time to keep a static bed due to the excessive off-period duration, it is indicated that there is an optimum off-period duration based on the heat transfer rate.