a b s t r a c tIn this study, heterogeneous Fenton-like degradation of reactive azo dye Rhodamine 6G in water was investigated over a CuFeZSM-5 zeolite catalyst prepared by hydrothermal synthesis. At initial pH of 3.4, a color removal of 100% was achieved after a reaction time of 45 min. TOC elimination was measured to be 51.8% after 2 h of oxidation. Initial decolorization rate was described by an equation of −r A0 = 4.56 × 10 2 e −24.83/RT C R6G,0 C 0.35 H 2 O 2 ,0 where R is in kJ/mol. The leaching of iron and copper cations from zeolite structure into the solution during oxidation was dependent on pH strongly. The regulation of pH from 6.5 (dye solution pH) to 3.4, increased leaching for iron from 0.7 to 0.8 mg/dm 3 and for copper from 1.4 to 2.1 mg/dm 3 . The copper was totally leached from the catalyst during the process at pH 3.4.

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This study presents an evaluation of the catalytic performances of Fe and Cu containing ZSM-5 zeolites for oxidation of Rhodamine 6G. Fe and Cu were loaded by ion exchange or through hydrothermal synthesis. The catalytic process was carried out in an aqueous solution using H2O2 as an oxidant. The catalyst prepared by hydrothermal synthesis showed the highest activity (100% decolorization, 59.1% aromatic degradation and 51.8% TOC removal at initial pH of 3.5). This catalyst was stable against leaching even at low pH. The change in activity of the catalysts prepared was attributed to incorporation of the Fe and Cu species with ZSM-5. Fe and Cu were in structural locations - in the framework - in the catalyst prepared by hydrothermal synthesis while there were extraframework cations or species in catalysts prepared by ion exchange. Incoporation of Cu into FeZSM-5 increased its catalytic activity. © 2010 Elsevier B.V. All rights reserved.TÜBİTAK and NASU project number 107M62

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