Metal–phenolic networks (MPNs) are novel supramolecular
materials with numerous applications in the field of advanced material
science and engineering due to their plentiful fascinating features.
Following the first assembling of MPN films on diverse solid surfaces
in 2013, MPN materials have attracted much attention in the membrane
technology field to improve membrane multifunctionality through membrane
surface or matrix modification for membrane structural stability,
durability, and filtration efficiency enhancements. Moreover, the
incorporation of inorganic nanomaterials, such as nanoparticles, nanotubes,
nanorods, and nanosheets, and hydrophilic polymers, for instance,
zwitterions and polyvinylpyrrolidone (PVP), can enable further improvements
of MPN-based membranes for diverse water filtration applications.
This review has critically summarized the recent MPN-based membrane
modifications and identified areas that need to be considered in further
research to enhance membrane durability, filtration performance, and
operational lifetime. Overall, it is foreseen that the novel membranes,
as well as an ever-widening scope of membrane applications based on
the MPN material, will constantly emerge.
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