The role of bathocuproine ͑BCP͒ buffer layer inserted between active layer and Al contact in photovoltaic cells based on phthalocyanine ͑Pc͒ and C 60 was investigated. Photoluminescence ͑PL͒ experiments show exciton quenching at the C 60 -Al interface to be strongly reduced by inserting BCP. Current-voltage characteristics of photovoltaic cells with planar geometry front electrode/ Pc/ C 60 / BCP/ Al show that BCP dramatically improves electron transport out of the C 60 film into the Al electrode. The tenfold increase in power conversion efficiency ͑͒ with BCP can mostly be attributed to the latter effect. BCP does not improve in photovoltaic cells with blend film geometry front electrode/Pc: C 60 / Al.

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