This article dedicated to study of few oscillating reactions in homogeneous systems. The experimental data and preliminary mechanism are reported. The authors affirm they find new type of oscillating processes-the reactions of carbonylation.

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The oscillatory modes of oxidative carbonylation reaction of two new substrates-2-methyl-3-butyn-2-ol and 2-propyn-1-ol in homogeneous system PdI 2 -KI-CO-O 2 -CH 3 OH are found. Borders of oscillatory areas are drawn, the basic products of reaction are identified, and probable processes routes are offered.