ABSTRAKPasir besi merupakan salah satu sumber daya alam yang melimpah di Indonesia terutama di pantai selatan Jawa Barat dan merupakan bahan dasar untuk bangunan serta industri logam.Kandungan mineral pasir besi tersebut umumnya adalah oksida logam seperti magnetit, hematit dan silika/kuarsa. Pada penelitian ini akan dilakukan analisa kuantitatif kandungan senyawa oksida logam (Fe 2 O 3 , Fe 3 O 4 ) dan kuarsa (SiO 2 ) sebagai identifikasi mineral bijih besi yang memiliki aspek ekonomis untuk industri logam.hasil analisa bahwa kandungan magnetite yang terdapat pada pasir besi secara kuantitatif dengan menggunakan X-Ray Diffraction (XRD) berbeda untuk setiap sampel. Untuk sampel pasir nonseparasi (TS) menghasilkan magnetite 24.27%, sampel tailing separasi ke-1 (SS1) menghasilkan magnetite 5.39% dan sampel consentrate separasi ke-3 (S3) menghasilkan 61.98% Kata Kunci : magnetite, hematite, Rietveld refinement PENDAHULUAN Pasir besi merupakan salah satu sumber daya alam yang melimpah di Indonesia terutama di pantai selatan Jawa Barat dan merupakan bahan dasar untuk bangunan serta industri logam. Kandungan mineral pasir besi tersebut umumnya adalah oksida logam seperti besi, timah dan silika/kuarsa. Salah satu bahan dasar yang dibuat menggunakan pasir besi adalah kandungan magnetit (Fe 3 O 4 ) yang digunakan sebagai bahan dalam pembuatan logam besi. Terlepas dari carut marutnya konflik pasir besi di Indonesia, memang harus ada sikap tegas dari Pemerintah dan penegak hukum. Dinas Pertambangan daerah akan ompong tanpa adanya tindakan dari aparat kepada penambang-penambang liar, namun akan lebih tak bergigi lagi jika pemerintah sebagai pembuat regulasi tidak memberikan sanksi sebesar-besarnya kepada pada penambang liar tersebut. Hal ini bukan untuk melarang kegiatan penambangan pasir besi, namun harus mengatur supaya semua pihak yang
The Infrared (IR) spectra usually assume the samples are 3D materials. Thus, it is difficult to identify functional groups in 2D materials at the edge and the center of the 2D surface. Therefore, it is crucial to introduce analysis methods that enable the investigation of 2D carbon materials such as graphene and its derivatives using IR spectra. This study calculates the infrared spectra of pyrene-like molecules as an insight for a simple analysis of graphene quantum dots using a semi-empirical method. These IR spectra were correlated to the electronic transition and charge distribution associated with functional groups. The IR spectra analysis focuses on comparing the pristine and functionalized molecule at the wavenumber 1400–2000 cm−1, especially to identify the C=C stretching mode and 3000–3500 cm−1 for C–H and OH stretching. Moreover, the determination of excitation spectra was carried out to analyze the electronic transition of the molecules in the ultraviolet–visible region (200–900 nm) calculated using ZINDO method. The investigation of the pyrene-like GQD permitted the identification of the edge and center surface functionalization in 2D carbon materials.
Iron sand is one of the abundant natural resources in Indonesia, especially on the south coast of Cidaun; West Java which is the basic material for building and metal industry. Iron mineral content is generally metal oxide such as magnetite, hematite and silica/quartz. Sand with iron content used in this study is derived from beach sand Desa Kertajadi, Kecamatan Cidaun, Kabupaten Cianjur, Jawa Barat. Then mass of 2 kg sand was separated using a magnetic separator in order to obtain magnetic and nonmagnetic mineral content. After nine rounds of separation takes two different types of samples that are no separation sand (TS) sample and concentrate in the third separation (S3) sample. The sample is then examined by X-Ray Diffraction (XRD) measurement and analyzed quantitatively using MAUD software to determine the content of Fe3O4 (magnetite) by using the Rietveld refinement method from XRD data. As the analysis result, the magnetite content contained in iron sand is counted quantitatively for each different sample. For iron sand samples (TS) yielding a 24.27 percent of magnetite and a third concentrate separation sample (S3) yields 61.98 percent.
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