This paper presents a technology for applying copper and silver films to cotton fabrics by combining photochemical and chemical methods for the reduction of the compounds of these metals. The resulting metal-containing films have inherent electrical conductivity of metals. All the main processes described in the work were carried out by means of the compounds being sorbed by the surface of the fabric when they were wetted in appropriate solutions. The aim of the work was to study the application of electrically conductive composite copper films on cotton fabrics. The tasks to achieve this aim were to perform scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction analysis to confirm that as a result of the experiment, CuCl with a semiconductor ability was formed on the surface of the sample. The driving force behind the photochemical reduction of copper and silver halides on cotton surfaces is that, as a result of the photooxidation of cellulose molecules in the fabric, copper monochloride is first formed on the cotton surface. Subsequently, the process of obtaining silver particles based on semiconductor silver chloride obtained as a result of the transformation of copper monochloride was carried out. The physicochemical and photochemical processes leading to the formation of monovalent copper chloride, which provides sufficient adhesion to the substrate, are considered. It is shown that in this case, the oxidation of monovalent copper also occurs with the formation of soluble salts that are easily removed by washing. Since the proposed technology does not require special equipment, and the chemical reagents used are not scarce, it can be used to apply bactericidal silver films to various household items and medical applications in ordinary laundries or at home. This article examines an affordable and simple technology for producing metal films on a cotton surface due to the presence of disadvantages (time duration, high temperature, scarce reagents, special installations, etc.) of a number of well-known methods in the production of chemical coatings.

Статья посвящена поверхностной модификации изотактического полипропилена путем радиационной прививки функциональных полярных групп с целью последующей металлизации полимерного материала. Представленные ИК-спектры, результаты измерения краевого угла смачивания модифицированного материала указывают на улучшение гидрофильности поверхности. Установлена степень прививки функциональных групп к поверхности изотактического полипропилена. Предложена схема поэтапного модифицирования поверхности полипропилена. Для получения токопроводящего слоя на поверхности модифицированного полипропилена использован низкотемпературный газо-фазный метод нанесения электропроводящих пленок фосфида меди. Приведены экспериментальные результаты, показывающие, что фосфид меди обладает электрической проводимостью и придает покрытию повышенную твердость.

This article discusses the method of obtaining phosphorus-containing components from cottrel dust from the industrial wastes of the New-Jambul phosphorus plant. Accumulated industrial waste heavily pollutes the environment and has a direct impact on all living things. Therefore, their processing is of special interest for the state and grant programs have been allocated in order to obtain new valuable substances. In order to solve these problems, a number of experimental works have been carried out to study the chemical and mineralogical composition and chemical structures during the heat treatment of cottrel dust—the waste of phosphorus production. The optimal parameters of the process of obtaining mono-calcium phosphate from cottrel dust were determined and the process of crystallization of mono-calcium phosphate was studied. A method has been developed for obtaining a phosphorus-containing fertilizer based on cottrel dust from the industrial waste of the New-Jambul phosphorus plant by means of sulfuric acid solutions. The advantage of the resulting phosphorus-containing fertilizer is that it has a high solubility and digestibility of phosphorus plants. They are also high in phosphorus-containing substances that ensure the growth and yield of agricultural plants. The developed method for obtaining phosphorus-containing fertilizers is aimed at reducing the accumulated industrial waste, which in turn allows you to regulate and improve the environmental situation in the region.