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Based on the rational design of heterojunction interface, a novel and efficient Bi25FeO40–Bi2WO6 heterostructure photocatalyst was successfully constructed by a facile hydrothermal process.

A new divalent ytterbium complex, [{(LPh)YbII(Et2O)(thf)}2(μ‐KI)] {LPh = Ph2Si(NAr)2, Ar = 2,6‐iPr2C6H3} (3), was synthesized by the reaction of [(LPh)YbIIII(thf)2] (2) and an excess of potassium. The bimetallic ytterbium(II) species with bulky diamido ligands are bridged by a KI molecule with cation–π interactions. These two complexes have been fully characterized, particularly by X‐ray crystallography.

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