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A facile strategy to synthesize the novel composite paper of graphene nanosheets (GNS) coated Co(3)O(4) fibers is reported as an advanced anode material for high-performance lithium-ion batteries (LIBs). The GNS were able to deposit onto Co(3)O(4) fibers and form the coating via electrostatic interactions. The unique hybrid paper is evaluated as an anode electrode for LIBs, and it exhibits a very large reversible capacity (∼840 mA h g(-1) after 40 cycles), excellent cyclic stability and good rate capacity. The substantially excellent electrochemical performance of the graphene/Co(3)O(4) composite paper is the result from its unique features. Notably, the flexible structure of graphenic scaffold and the strong interaction between graphene and Co(3)O(4) fibers are beneficial for providing excellent electronic conductivity, short transportation length for lithium ions, and elastomeric space to accommodate volume varies upon Li(+) insertion/extraction.

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The expansion of weed infestation has increased the demand on new herbicides. A series of novel galactosyl moietyconjugated furylchalcones was facilely synthesized in which the furyl group (A ring) was combined with the substituted benzene group (B ring), and a galactosyl moiety was introduced. All these galactosyl furylchalcones were predicted to be phloem-mobile. Most of the galactosyl furylchalcones significantly promoted early seedling growth of sorghum and barnyardgrass under dark conditions, but all of them revealed considerable anti-growth ability on illuminated pot plants; especially, 1-(3′-(4″-O-β-Dgalactopyranosyl)furyl)-3-(4″-nitrophenyl)-2-en-1-one (B 11 ) had a better herbicidal activity against rapeseed and Chinese amaranth than haloxyfop-R-methyl. The median efficient concentrations (EC 50 ) of compound B 11 against cucumber and wheat were 9.55 and 26.97 mg/L, respectively, also showing a stronger suppressing capacity than 2,4-D. Molecular docking with phosphoenolpyruvate carboxylase protein showed a stable binding conformation in which the galactosyl group interacted with LYS363 and GLU369, the furan ring and carbonyl bound with ARG184, and the crosslink of the nitro group with GLU240 formed a salt bridge. The results demonstrate that galactosyl furylchalcones possess the great potential as new herbicides for weed management, and further evaluations on more weeds are required for practical application.

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