In the present work, we have studied the temporal evolution of aluminum alloy plasma produced by the fundamental (1064 nm) of a Q-switched Nd:YAG laser by placing the target material in air at atmospheric pressure. The four Al I-neutral lines at 308.21, 309.27, 394.40 and 369.15 nm as well as Al II-ionic lines at 281.61, 385.64 and 466.30 nm are used for the determination of the electron temperature Te using Saha-Boltzmann plot method. The neutral aluminum lines were found to suffer from optical thickness which manifested itself on the form of scattered points around the Saha-Boltzmann line. The isolated optically thin hydrogen Hα-line at 656.27 nm appeared in the spectra under the same experimental conditions was used to correct the Al I-lines which contained some optical thickness. The measurements were repeated at different delay times ranging from 1 to 5 µs. The comparison between the deduced electron temperatures from aluminum neutral lines before correction against the effect self-absorption to that after correction revealed a precise value in temperature. The results sure that, in case of the presence of self-absorption effect the temperature varies from (1.4067 -1.2548 eV) as the delay time is varied from 0 to 5 µs. Whereas, in the case of repairing against the effect, it varies from (1.2826 -0.8961 eV) for the same delay time variation. KeywordsLaser Induces Breakdown Spectroscopy (LIBS), Self-Absorption (SA), Saha-Boltzmann Plot, Delay Time (Td), Electron Number Density (Ne), Plasma Temperature (Te) S. A. M. Mansour 80