Electrochromic nickel oxyhydroxide films were formed by an electrodeposition method from 0.005 M NiSO4+0.015 M (NH4)SO4 solution, and their memory characteristics, response time and operation lifetime were investigated. The films prepared were porous with a network structure. They were colorless and transparent in a lower oxidation state [Ni(OH)2], but were dark brown in a higher oxidation state [NiOOH]. By heat-treating the films at 250degC for 15 minutes, electrochromic characteristics such as the operation lifetime could be remarkable improved.
Since corpora amylacea is concentrated in the high density fraction in the subcellular fractionation of autopsy brain. It is suspected that inorganic materials accumulate in corpora amylacea. Therefore, elemental analyses of partially purified corpora amylacea from autopsy brain from a patient with Alzheimer's disease and those from brain of a non-demented patient were performed by the X-ray microprobe method. Prominent peaks of sodium, phosphorus, sulphur and chloride were observed, and mapping analyses confirmed that these elements were actually contained within the corpora amylacea. A similar result was obtained using cryostat sections. Corpora amylacea are characteristically distributed along the margin of blood vessels, beneath the pial border of the hippocampus and in the subependymal zones of ventricles of aged brains, namely in the vicinity of blood and cerebrospinal fluid. From this distribution and from the results of the present paper, we suggest that corpora amylacea play a role in the absorption and accumulation of inorganic materials which have been extravasated from blood and cerebrospinal fluid (CSF) and taken up by astrocytes. This may reflect alteration of the blood-brain and blood-CSF barriers in the ageing brain.
A new method of formation of electrochromic MoO3 thin oxide film on electric conducting glass (ITO glass) has been investigated for use in place of the conventional vacuum evaporation method. The ITO glass was cathodically electrolyzed in an aqueous solution of 0.007 mol/l lithium molybdate at a constant current density of ca. 3 A/m2 at 25°C. Blue, conductive and adhesive oxide film was obtained. Cycles of the coloration and bleach were repeated in the propylene carbonate solution of lithium perchlorate. A good reversibility was obtained.
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