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We construct for the first time a H2O2-free electrochemical peptide biosensor based on Au@Pt bimetallic nanorods in neutral substrate solutions for highly sensitive detection of matrix metalloproteinase 2.

Spark ablation in gas (SAG) technology has the characteristics of being green, fast quenching, fast dynamics and specializes in producing metallic nanoparticles with a clean surface, small size, and abundant defects.

A series of transition metal oxides or mixed oxides supported nano-Au catalysts were prepared for the selective oxidation of glycerol to glyceric acid using 3% H2O2. It was found that the composition and structure of supports significantly influenced the catalytic performance of catalysts. The mesoporous trimetal mixed oxide (CuNiAlO) supported nano-Au catalysts were more active in comparison with the others. In the present catalytic system, the highest glycerol conversion was 90.5%, while the selectivity of glyceric acid could reach 72%. Moreover, the catalytic performance remained after 11 times of reaction.