Full varieties of strongly correlated electron phenomena have been found in the filled skutterudite systems, by changing the constituent elements. The unique crystal structure leads to novel features even in the systems containing rare earth elements with plural number of 4f -electrons. According to the intensive competitions and cooperation among experimental and theoretical research works, remarkable progress has been made in sorting out several basic origins that bring about the variety of this system, such as the strong c-f hybridization, the small CEF level splitting, the orbital degree of freedom (multipoles), and the positional degree of freedom within a pnictogen cage. However, there still remain many attractive questions to be answered.
We report resistivity, nuclear quadrupole resonance (NQR), and magnetization measurements under high pressures in a novel heavy fermion compounds SmOs4Sb12. The resistivity and nuclear spin-lattice relaxation rate 1/T1 show the coherent behavior below a characteristic temperature T * = 20 − 25 K at ambient pressure. Nuclear spin-spin relaxation rate 1/T2 was found to show a peak of electrical origin around T * . Some charge fluctuation is considered to play an important role in the Kondo effect of SmOs4Sb12. On the other hand, the magnetization at low temperature does not increase under pressures, although the transition temperature increases. The NQR signals are strongly suppressed around the transition temperature and vanishes at low temperatures. These suggest that the ordered state in SmOs4Sb12 is not simple ferromagnetism.
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