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A new photochromic diarylethene derivative with a triazozoyl hydrazine unit has been designed and synthesized.

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A novel photochromic diarylethene was synthesized successfully containing a phthalazine unit. Its multistate fluorescence switching properties were investigated by stimulating with UV/vis lights and Al3+/EDTA. The synthesized diarylethene displayed excellent selectivity to Al3+ with a distinct fluorescence change, revealing that it could be used as a sensor for fluorescence identification of Al3+, and a logic circuit was constructed by utilizing this diarylethene molecular platform. Moreover, it also exhibited a high accuracy for the determination of Al3+ in practical water samples.