Mountain areas in China account for 69% of the total land area; however, it is still an urgent that we grasp the special ecological structure of mountain areas and maximize the resource advantages of mountain areas under the principle of maintaining a certain ecological level. In this paper, Landsat 5, Landsat 8 and Sentinel-2A images were used as data sources to monitor and analyze land development and ecological change in Gui ’an in 2010, 2013, 2016, 2019 and 2021, so as to explore ecological maintenance mechanisms. Firstly, random forest classification based on multi-source remote sensing data was used to classify land, and the five phases of land-use change were assessed using quantitative analysis, in order to analyze the mountain region’s land-use-change characteristics at different stages of development. The results show that Gui ’an has the “two-stage”, rapid-development, rapid-recovery mode. Each stage includes a development-and-expansion period and a construction-and-protection period. In the construction period, ecological recovery construction will be emphasized, and the change intensity and rate of the second stage are lower than that of the first stage. Secondly, using a remote sensing ecological index, vegetation coverage, and a landscape index, an ecological evaluation model of the study area was constructed to analyze changes in the ecological environment and its protection in the process of land development. The ecological maintenance status of the five stages was quantitatively monitored using the analysis methods of difference change and coefficient of variation. The results showed that in the first stage of land development and expansion, the landscape pattern and ecological quality fluctuated greatly, and the proportion of ecological quality of an excellent grade decreased by 28.46%. However, in the second stage, the change slowed down and remained unchanged, and gradually moved to the middle and upper level. The results show that there is a close relationship between ecological maintenance and the land development mode, and new mountain towns can maintain ecological quality and achieve sustainable development through a reasonable land development mode. At the end of this paper, the factors affecting the ecological maintenance capacity of Gui ’an are discussed, providing effective reference material and development models for the development of mountainous areas.