The need to minimize surfactant adsorption on rock surfaces has been a challenge for surfactant-based, chemicalenhanced oil recovery (cEOR) techniques. Modeling of adsorption experimental data is very useful in estimating the extent of adsorption and, hence, optimizing the process. This paper presents a mini-review of surfactant adsorption isotherms, focusing on theories of adsorption and the most frequently used adsorption isotherm models. Two-step and four-region adsorption theories are well-known, with the former representing adsorption in two steps, while the latter distinguishes four regions in the adsorption isotherm. Langmuir and Freundlich are two-parameter adsorption isotherms that are widely used in cEOR studies. The Langmuir isotherm is applied to monolayer adsorption on homogeneous sites, whereas the Freundlich isotherm suites are applied to multilayer adsorption on heterogeneous sites. Some more complex adsorption isotherms are also discussed in this paper, such as Redlich− Peterson and Sips isotherms, both involve three parameters. This paper will help select and apply a suitable adsorption isotherm to experimental data.
Empirical equations for estimating viscosity: above, at, and below the bubble point pressure were developed based on data from Saudi Arabian crude oils. Both statistical and graphical techniques have been employed to evaluate these equations as compared to other published crude oil viscosity correlations using the same data. It is shown that the developed correlations provide more accurate estimates of viscosity in all three regimes of pressure. Introduction Viscosity is the measure of resistance to fluid flow. Knowledge of viscosity is required in reservoir simulation, fluid flow through porous media and pipelines, well testing, and design of production pipelines, well testing, and design of production equipment. Crude oil viscosity can be classified into three regimes. Bubble Point Oil Viscosity It is the viscosity of crude oil at the bubble point pressure and a given temperature. point pressure and a given temperature. Oil Viscosity Above the Bubble Point It is defined as the crude oil viscosity at a pressure higher than the bubble point pressure and a pressure higher than the bubble point pressure and a given temperature. Oil Viscosity Below the Bubble Point It is the viscosity of crude oil below the bubble point pressure and a given temperature. With the point pressure and a given temperature. With the lowering of pressure below the bubble point pressure, gas is released leaving behind a saturated oil at the new pressure. When the pressure is lowered to atmospheric pressure, there is no dissolved gas left in the oil and such oil is called dead oil whose viscosity is referred to as the dead oil viscosity. In many cases, the only information available from PVT analysis of an oil sample are simple and readily PVT analysis of an oil sample are simple and readily measurable parameters such as gas relative density, oil API gravity, and gas-oil ratio. Direct viscosity measurements or complete compositional analyses of crude oils are expensive, therefore, empirical correlations, which are functions of these readily measurable PVT properties, are used to estimate oil viscosity. A number of different viscosity correlations have been presented in the literature, as shown in Table 1, and reviewed in detail by Khan. Most of these correlations were based on limited data from different geographical locations which introduced large potential errors. Moreover, these correlations involve complex mathematical expressions which do not explain the behavior of oil viscosity very clearly. In this study, an alternative approach to viscosity correlation development, along with new viscosity equations have been derived. In this approach, emphasis is placed on the natural variation of viscosity with PVT parameters. In this paper, the new correlations and four of the published correlations, namely those of Beal, Chew and Connally, Beggs and Robinson, and Vazquez, will be evaluated using Saudi Arabian crude oil viscosity data which was used to develop the new correlations. VISCOSITY DATA This study utilized viscosity data for 75 bottom hole samples taken from 62 Saudi Arabian oil reservoirs. P. 251
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.