Two conjugated ethynyl-linked oligomers, oligo(benzodithiophene-ethynylene-benzothiadiazole) (O1) and oligo(benzodithiophene-ethynylene-carbazole) (O2), were synthesized by Sonogashira coupling reaction. Their degrees of polymerization were 7 and 10, respectively. Their photophysical and electrochemical properties were investigated. O1 exhibitd two strong absorption bands at 404 nm and 483 nm, and O2 at 401 nm and 429 nm. The results of UV-Vis, cyclic voltammetry (CV) and theoretical calculations showed that O1 has a narrower band gap than O2. The conductivities of O1 and O2 were 1.05×10 −15 and 6.98×10 −16 S/cm, respectively, and would increase to 1.23×10 −10 and 1.05×10 −10 S/cm after doping with iodine.
Four-level active neutral point clamped (ANPC) inverter becomes increasingly widely used in the renewable energy industry since it offers one more voltage level without increasing the total number of active switches compared to the three-level ANPC inverter. The model predictive current control (MPCC) is a promising control method for multi-level inverters. However, the conventional MPCC suffers from high computational complexity and tedious weighting factor tuning in multi-level inverter applications. A low complexity MPCC without weighting factors for four-level ANPC inverter is proposed in this paper. The computational burden and voltage vector candidate set are reduced according to the relationship between voltage vector and neutral point voltage balance. The proposed MPCC shows excellent steady-state and dynamics performances while ensuring the neutral point voltage balancing. The efficacy of the proposed MPCC is verified by simulation and experimental results.
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