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Compacted vermicular (CV) graphitization cast iron is the name given to graphitization cast iron where the shape of the graphite looks like a vermicular. Castability and the thermal conductivity of CV graphitization cast iron is similar to those of Grey iron, while the strength of CV graphitization cast iron is similar to that of ductile iron. The thin film of diamond-like carbon (DLC) is one of the amorphous carbon thin films. It has various characteristics which are similar to those of diamond, such as high hardness, lubricity, abrasion resistance, chemical stability, electrical insulating properties and optical transparency. In this study, wear characteristics of Graphite Compacted Vermicular (GCV) material were investigated in accordance with changes in DLC coating time. The obtained results are as follows: the microstructure of GCV340 showed complex tissue with eccentric graphite and spherical graphite. The friction coefficient shows under 0.2 in all specimens. After enduring the wear test until 2000 m, the coating layer of the DLC coating specimen of 90 minute hardly showed any damage. It had only partial damage after taking the wear test until 2000 m. The friction coefficient was also the lowest.