Electrochemical strategy has been the powerful approach for the synthesis of valuable intermediates, in particular heterocyclic motifs. It has proven to be an environmentally benign, highly effective and versatile platform...

Concise total syntheses of naturally occuring antiviral indolosesquiterpene alkaloids, xiamycin C (2a), D (2b), E (2c) and F (2d) have been achieved via a late-stage oxidative d-Csp3-H functionalization of an...

First total synthesis of a naturally occurring sesquiterpenoid, (+)-ar-macrocarpene, has been achieved via a key [3,3]-sigmatropic rearrangement effecting reductive transposition through allylic diazene rearrangement (ADR).

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