Eco-friendly hydrophobic coatings were fabricated on tiles via the drop-casting process. Sugarcane bagasse waste ash (SBA) was used as a silica source and dimethyldiethoxysilane (DMDEOS) was used as a surface functionalizing agent. The elemental composition of SBA was measured using X-ray fluorescence (XRF) and energy-dispersive spectroscopy (EDS) techniques. The surface morphology of SBA was analyzed through the field-emission scanning electron microscopy (FESEM) technique. The surface wettability of SBA coated tiles was evaluated by determining the static water contact angle (WCA). XRF studies showed that the impurities were removed, and the silica content was enriched by the acid treatment. SBA coated tiles showed good hydrophobicity with a WCA of 135°. The high hydrophobicity of the coated tiles may be attributed to the increase of surface roughness by SBA. Moreover, the SBA coating was successfully tested on various substrates such as tiles, brick, glass, and cotton cloth. SBA coated glass substrate was more durable compared to other substrates at normal room temperature.