The time-resolved luminescence technique developed by Infelta et. al.
1 has been used to measure the aggregation numbers (number
of surfactant molecules per aggregate) for microemulsions containing
cetyltrimethylammonium bromid (CTAB) and cetyltrimethylammonium
chloride (CTAC) as surfactants. Microemulsions are transparent
dispersions of two immiscible liquids (e.g. oil and water) stabilized
by an emulsifier comprising a surfactant and cosurfactant (Figure 1).
The microemulsion aggregates typically have radii of 100-500
Angstroms. Microemulsions are being studied for possible use in
decontamination of toxic organophosphorus compounds.
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