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Syntheses and Relative Stability of (D3)‐Trishomocubane (Pentacyclo= (6,3,O,O2,5,O3,10,O5,9)undecane), the Pentacycloundecane Stabilomer.

A new route for the synthesis of thiocarbamates using a transition metal complex and CO as a replacement for phosgene has been discovered. The complex (PPh 3 ) 2 PdCl 2 reacts with N-benzylmethylamine, 4-chlorobenzenethiol, and CO to selectively generate a thiocarbamate. Kinetic studies and the isolation of several intermediates in this reaction allow for the proposal of a mechanistic scheme.