[1] We have performed a series of co-compression experiments on Au, Pt, Mo, MgO and NaCl to extend internally consistent pressure calibration and characterize shear strength of pressure media to 2.5 Mbar. Measured unit cell volumes of calibrants show differences between existing pressure scales of $10% above 2 Mbar. A new comprehensive pressure scale is proposed in good agreement with recent reduced shock isotherms for Au, Mo and Pt and with internal agreement to 3% at Mbar pressures. Deviatoric stresses were analyzed for each material based on diffraction line broadening and line shifts due to anisotropic strain. The measured strength of Ne at 2.5 Mbar is 8 GPa. Diffraction line width analysis suggests that deviatoric stress conditions at 2.5 Mbar are similar for He and Ne media.
Phase transitions and equations of state of the alkaline earth fluorides CaF 2 , SrF 2 , and BaF 2 were examined by static compression to pressures as high as 146 GPa. Angle-dispersive x-ray diffraction experiments were performed on polycrystalline samples in the laser-heated diamond-anvil cell. We confirmed that at pressures less than 10 GPa all three materials undergo a phase transition from the cubic ͑Fm3m͒ fluorite structure to the orthorhombic ͑Pnam͒ cotunnite-type structure. This work has characterized an additional phase transition in CaF 2 and SrF 2 : these materials were observed to transform to a hexagonal ͑P6 3 / mmc͒ Ni 2 In-type structure between 63-79 GPa and 28-29 GPa, respectively, upon laser heating. For SrF 2 , the Ni 2 In-type phase was confirmed by Rietveld refinement. Volumes were determined as a function of pressure for all high-pressure phases and fit to the third-order Birch-Murnaghan equation of state. For CaF 2 and SrF 2 , the fluorite-cotunnite transition results in a volume decrease of 8 -10 %, while the bulk modulus of the cotunnite-type phase is the same or less than that of the fluorite phase within uncertainty. For all three fluorides, the volume reduction associated with the further transition to the Ni 2 In-type phase is ϳ5%. The percentage increase in the bulk modulus ͑⌬K͒ across the transition is greater when the cation is smaller. While for BaF 2 , ⌬K is 10-30 %, ⌬K values for SrF 2 and CaF 2 are 45-65 % and 20-40 %. Although shock data for CaF 2 have been interpreted to show a transition to a highly incompressible phase above 100 GPa, this is not consistent with our static equation of state data.
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