Geminal diauration of [Ph3PAu(aryl)] complexes has been investigated to model the intermediacy of geminally diaurated gold(I)–vinyl complexes in catalysis (see scheme). The results advance our understanding of the factors influencing the stability, reactivity, and dynamics of these organometallic intermediates.
Die geminale Diaurierung von [Ph3PAu(Aryl)]‐Komplexen wurde als Modell untersucht, um Einblick in die intermediäre Bildung von geminalen diaurierten Gold(I)‐Vinylkomplexen in der Katalyse zu gewinnen (siehe Schema). Die Ergebnisse tragen zum Verständnis der Faktoren bei, die die Stabilität, Reaktivität und Dynamik dieser metallorganischen Zwischenstufen bestimmen.
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