No abstract

Histidyl-histidine (His-His) has been synthesized in a yield of up to 14.4% under plausible prebiotic conditions using histidine (His), cyanamide, and 4-amino-5-imidazole carboxamide. A trace amount of His trimer was also detected. Because the imidazole group of His is involved in a number of important enzymatic reactions, and His-His has been shown to catalyze the prebiotic synthesis of glycyl-glycine, we expect this work will stimulate further studies on the catalytic activities of simple His-containing peptides in prebiotic reactions.

Thirty years ago it was suggested that comets impacting on the primitive Earth may have represented a significant source of terrestrial volatiles, including some important precursors for prebiotic synthesis (Oró, 1961, Nature 190: 389). This possibility is strongly supported not only by models of the collisional history of the early Earth, but also by astronomical evidence that suggests that frequent collisions of comet-like bodies from the circumstellar disk around the star beta Pictoris are taking place. Although a significant fraction of the complex organic compounds that appear to be present in cometary nuclei were probably destroyed during impact, it is argued that cometary collisions with the primitive Earth represented an important source of both free-energy and volatiles, and may have created transient, gaseous environments in which prebiotic synthesis may have taken place.

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We present the technical design, construction and testing of the Colibri telescope array at Elginfield Observatory near London, Ontario, Canada. Three 50-cm telescopes are arranged in a triangular array and are separated by 110–160 m. During operation, they will monitor field stars at the intersections of the ecliptic and galactic plane for serendipitous stellar occultations (SSOs) by trans-Neptunian objects (TNOs). At a frame rate of 40 frames per second (fps), Fresnel diffraction in the occultation light curve can be resolved and, with coincident detections, be used to estimate basic properties of the occulting object. Using off-the-shelf components, the Colibri system streams imagery to disk at a rate of 1.5 GB/s for next-day processing by a custom occultation detection pipeline.The imaging system has been tested and is found to perform well, given the moderate site conditions. Limiting magnitudes at 40 fps are found to be about 12.1 (temporal SNR = 5, visible light Gaia G band) with time-series standard deviations ranging from about 0.035 mag to >0.2 mag. SNR is observed to decrease linearly with magnitude for stars fainter than about G = 9.5 mag. Brighter than this limit, SNR is constant, suggesting that atmospheric scintillation is the dominant noise source. Astrometric solutions show errors typically less than ±0.3 pixels (0.8 arc seconds) without a need for high-order corrections.