Magnetic and superconducting properties of La2‑x
Sr
x
CuO4 nanoparticles
are systematically studied as a function of particle size and Sr doping.
Through the magnetization and electron spin resonance measurements,
it was found that the suppression of superconductivity and enhancement
of ferromagnetism were observed simultaneously with decreasing particle
size, which should be related to the uncompensated Cu2+ spins and oxygen defects due to the increasing role of finite size.
On the other hand, although Sr doping will introduce more uncompensated
spins to the La2‑x
Sr
x
CuO4 nanoparticles, the low temperature
ferromagnetism is reduced. The results suggest that the suppression
of superconductivity and the appearance of ferromagnetism for the
nanoparticles may be closely related to the destruction of antiferromagnetic
correlation in CuO2 planes.
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