All-solid-state donor/acceptor planar-heterojunction (PHJ) hybrid solar cells are constructed and their excellent performance measured. The deposition of a thin C60 fullerene or fullerene-derivative (acceptor) layer in vacuum on a CH3 NH3 PbI3 perovskite (donor) layer creates a hybrid PHJ that displays the photovoltaic effect. Such heterojunctions are shown to be suitable for the development of newly structured, hybrid, efficient solar cells.
This study successfully demonstrates the application of inorganic p-type nickel oxide (NiOx ) as electrode interlayer for the fabrication of NiOx /CH3 NH3 PbI3 perovskite/PCBM PHJ hybrid solar cells with a respectable solar-to-electrical PCE of 7.8%. The better energy level alignment and improved wetting of the NiOx electrode interlayer significantly enhance the overall photovoltaic performance.
In this article, we present a new paradigm for organometallic hybrid perovskite solar cell using NiO inorganic metal oxide nanocrystalline as p-type electrode material and realized the first mesoscopic NiO/perovskite/[6,6]-phenyl C61-butyric acid methyl ester (PC61BM) heterojunction photovoltaic device. The photo-induced transient absorption spectroscopy results verified that the architecture is an effective p-type sensitized junction, which is the first inorganic p-type, metal oxide contact material for perovskite-based solar cell. Power conversion efficiency of 9.51% was achieved under AM 1.5 G illumination, which significantly surpassed the reported conventional p-type dye-sensitized solar cells. The replacement of the organic hole transport materials by a p-type metal oxide has the advantages to provide robust device architecture for further development of all-inorganic perovskite-based thin-film solar cells and tandem photovoltaics.
The application of the biomaterial dielectrics made of thermally crosslinking natural proteins without any additives in fabricating organic electronics is highlighted. The gate dielectrics of organic field‐effect transistors (OFETs) are prepared by the thermal treatment of the chicken albumen film taken directly from a fresh egg. Flexible OFETs and the complementary inverters fabricated with albumen dielectrics are demonstrated.
The performance of hybrid perovskite-based light-emitting diodes (LEDs) is markedly enhanced by the application of a NiO electrode interlayer and moderate methylamine treatment. A hybrid perovskite-based LED exhibits a peak luminous efficiency of 15.9 cd A biased at 8.5 V, 407.65 mA cm , and 65 300 cd m , showing a distinctive impact for future applications.
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