With a new polycarbonate-film-based
dry transfer method, we successfully
fabricated twisted stacked black phosphorus. Optical characterization
showed the overlapping area had special optical response, and high-frequency
Raman spectroscopy showed unexpected blue shifts in Ag
1 and Ag
2 modes. Density functional theory
(DFT) calculations confirmed these blue shifts in twisted bilayer
black phosphorus, and revealed significant interlayer coupling effects.
Charge distribution calculations indicated other interactions beyond
van der Waals force may exist in twisted bilayer black phosphorus.
This finding may cast some insight on phonon modulation effect and
give some potential applications such as optical filters and infrared
photodetectors.
Abstract:In this work, a series of quaternary Al x In y Ga 1−x−y N thin films have been successfully achieved using metal organic chemical vapor deposition (MOCVD) method with adjustable trimethylaluminum (TMA) flows. Surface morphology and optical properties of Al x In y Ga 1−x−y N films have been evaluated. The indium segregation effect on the enhancement of UV luminescence emission in Al x In y Ga 1-x-y N films with increasing TMA flows was investigated. Our results shed some lights on future optical materials design and LED/LD applications.
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