[1] Characteristic vegetation and biofuels in major ecosystems of southern Africa were sampled during summer and autumn 2000 and burned under semicontrolled conditions. Elemental compositions of fuels and ash and emissions of CO 2 , CO, CH 3 COOH, HCOOH, NO X , NH 3 , HONO, HNO 3 , HCl, total volatile inorganic Cl and Br, SO 2 and particulate C, N, and major ions were measured. Modified combustion efficiencies (MCEs, median = 0.94) were similar to those of ambient fires. Elemental emissions factors (EF el ) for CH 3 COOH were inversely correlated with MCEs; EF el s for heading and mixed grass fires were higher than those for backing fires of comparable MCEs. NO X , NH 3 , HONO, and particulate N accounted for a median of 22% of emitted N; HNO 3 emissions were insignificant. Grass fires with the highest EF el s for NH 3 corresponded to MCEs in the range of 0.93; grass fires with higher and low MCEs exhibited lower EF el s. NH 3 emissions for most fuels were poorly correlated with fuel N. Most Cl and Br in fuel was emitted during combustion (median for each = 73%). Inorganic gases and particulate ions accounted for medians of 53% and 30% of emitted Cl and Br, respectively. About half of volatile inorganic Cl was HCl indicating significant emissions of other gaseous inorganic Cl species. Most fuel S (median = 76%) was emitted during combustion; SO 2 and particulate SO 4 2À accounted for about half the flux. Mobilization of P by fire (median emission = 82%) implies large nutrient losses from burned regions and potentially important exogenous sources of fertilization for downwind ecosystems.

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