In the title compound, C22H21BrO, other than the Br atom, the non-H atoms are approximately co-planar [maxium deviation = 0.178 (2) Å] and the alkoxy chain shows an all-anti conformation. A weak intermolecular C—H⋯Br hydrogen bond contributes to the stabilization of the crystal structure.
The title molecule, C5H4O2S3, consists of a planar [mean deviation = 0.020 (1) Å] 1,3-dithiole-2-thione unit with an ethylenedioxy group in the 4,5-positions. The dioxine ring is in a twist-chair conformation.
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