Nanocrystalline cerium(IV) oxide (CeO2) powders have been prepared by adding hydrazine monohydrate to an aqueous solution of hydrous cerium nitrate (Ce(NO3)3·6H2O), followed by washing and drying. The lattice parameter of the as‐prepared powder is a= 0.5415 nm. The powder characteristics and sinterability of reactive CeO2 have been studied. The surface areas of powders that have been heated at low temperatures are high, and these surface areas do not decrease to 10 m2/g until the temperature is >1200°C. Crystallite size and particle size are strongly dependent on the heating temperature. Optimum sintered densities are obtained by calcining in the temperature range of 700°–800°C. Ceramics with almost‐full density can be fabricated at a temperature as low as 1150°C.
An automatic coagulant dosage control technology for water purification plants was developed to deal with rapid changes of feed water quality. Control logic was developed to decide coagulant dosage based on aluminum concentration in the mixing tanks. A coagulant-sedimentation process apparatus was installed in December 2010 in a water purification plant, and the coagulant dosage control test using feed water was started. The developed system was confirmed to be effective for managing settled water turbidity and adequacy of coagulant dosage. For actual changes of feed water quality at the water purification plant over more than one year, the developed system was able to maintain settled water turbidity at less than 1.0 mg-kaolin/L in the period of high feed-water turbidity.
An automatic coagulant dosage control technology for water purification plants was developed to deal with rapid changes of raw water quality parameters. Control logic was developed to decide coagulant dosage based on aluminum concentration in rapid mixing tank water based on results of semi-pilot scale experiments. This logic enabled quick feedback on the excess or lack of coagulant. It was found that the aluminum residual rate, which was proposed as an indicator of coagulation reactions, could be given as a function of coagulant dosage and turbidity. The effectiveness of the control logic was verified in semi-pilot scale experiments. Settled water turbidity was within ±0.5 NTU of target value even when raw water turbidity increased rapidly up to 100 NTU.
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