In the paper, seven new azide chalcones 5a-5g were synthesized from 2,4-dihydroxyacetophenone in good yields via a 3-step procedure including selective O-alkylation with 1,2-dichloroethane, nucleophilic substitution with sodium azide and Claisen-Schmidt condensation reaction with different aldehydes 4a-4g. The structure of the azides chalcones was elucidated by spectroscopic methods such as NMR and HR-ESI-MS spectra.
Marine microalgae are an important source of raw materials for the extraction of highly bioactive substances for humans and domestic animals. In this study, the biological characteristics and the ability to grow biomass of green marine microalga of Dunaliella tertiolecta NY isolated from seawater of Namyit Island belonging to Spratly Islands, Vietnam (in May-June, 2021) was presented. Scientific name of the strain Dunaliella tertiolecta NY based on morphological characteristics and analysis of the sequence of rDNA ITS1-5.8S-ITS2 region was identified (with accession number of this gene region of this strain was supplied on the GenBank is OM 101011). At the best conditions for the growth (i.e. Walne medium, initial cell density of 2.0 x 106 cells/mL, growth temperature of 30oC, light intensity of 60 - 100 µmol/m2s, pH 7, salinity of 30-40‰), highest NY strain cell density of 8.63 x 106 cells/mL was obtained after 15 days of culture. The microalga D. tertiolecta NY was also successfully cultured on a pilot scale in the plastic bottles 10 L and closed photobioreactors 20 - 100 L resulting in a high biomass productivity of 285 mg/L/day and a biomass rich in polyunsaturated fatty acids such as gamma - linolenic acid (C18:3 ω-6; 5.07±0.59 % of total fatty acid - TFA), alpha - linolenic acid (ALA, C18:3 ω-3, 61.79±1.98 % of TFA) and stearidonic acid (SDA; C18: 4 ω-3, 1.59±0.65 % of TFA) qualified for the extraction of value bioactive compounds.
Desalination and treatment of wastewater has become critical for Asia regions with water scarcity. In this work, the concept of thin-film distillation equipped with a porous condenser (FDPC) was considered for its implementation in a tropical climate of Vietnam. It was found that samples with a concentration of biocide of 0.5 wt.% possessed lower biofouling, in contrast to the neat membranes. The FD-PC module was developed and water desalination experiments were conducted in Russia and Vietnam. The experiments showed high reproducibility of the results; in particular, the evaporation rate was (4.9/3.0) kg/m2h in Russia and (4.1/2.0) kg/m2h in Vietnam. In addition, as part of this work, the optimal configuration of the installation was calculated using solar collectors as the main energy source. The calculation showed high energy efficiency: specific energy consumption 0.1–0.5 kWh/m3.
In this paper, a manufacturing process of eco-friendly preservative oil from Basa fish grease of Agifish company was shown (called BDO-VN). The obtained product was examined to protect CT3 steel and blackened CT3 steel by using natural and accelerated test method. The results pointed out that the BDO-VN oil preserved well CT3 steel after testing 2 months, blackened CT3 steel after testing 3 months by natural test method.
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