Reaction of tBuPHz (1) with (Me3SiCH2)Jn (2) in the presence PzInz ring with alternating P -In bonds and crystallizes in the of Ag+ ions leads to [(Me3SiCH2)21nPHtBu]2 (3). According to monoclinic space group C2/c. an X-ray structure analysis, 3 forms a four-membered planar
Die Reaktion von (Me3SiCH2)3 In mit AdPH2 (Ad = Adamantyl) führt in Gegenwart katalytischer Mengen AgNO3 unter Abspaltung von Tetramethylsilan in 30% Ausbeute zu [(Me3SiCH2)2InP(H)Ad]2 1. Die Kristallstruktur von 1 wird diskutiert.
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