The reaction of 3H,6H‐1,2‐dithiolo[4,3‐c]1,2‐dithiole‐3, 6‐dithione (1) with primary aliphatic amines (8a,b) gives 3H,6H‐3,6‐bisalkylimino‐1,2‐dithiolo[4,3‐c]1,2‐ dithiole (9a,b), 3H,3‐N‐alkylamino‐5‐N‐alkylthiocarbamido‐1, 2‐dithiolium‐4‐thiolate (10a,b) and 3H,3‐N‐alkylimino‐4‐alkylamino‐5‐N‐alkylthiocarbamido‐1,2‐dithiole (11a,b). The compounds 9‐11 can be formed from one another. The compounds 10a,b react with nickel chloride to the stable complexes 14a,b. In basic medium 10 gives the salt of 3H,3N‐alkylthiocarbamido‐1,2‐dithiole‐4‐thiolate 15, which reacts with methyl iodide to 3H,3N‐alkylimino‐5‐N‐alkylthiocarbamido‐4‐methylthio‐1,2‐dithiole 16.

Das thermische Verhalten der Poly(bis-alkylthio-acetylen)e wurde im Temperaturbereich von 30°C bis 600°C untersucht. Aus den Ergebnissen der thermischen Analyse, aus "C-Festkorper-NMR-und ESR-Messungen an den festen Thermolyseruckstanden und der Untersuchung der fliichtigen Pyrolyseprodukte werden mogliche Abbaureaktionen abgeleitet. Fur einen weiten Zeit-und Temperaturbereich wird fur Poly(bis-methylthio-acetylen) ein einfaches kinetisches Modell formuliert. Organic electron conductors and precursors. XIII. Investigation of the thermal behaviour of poly(bis-alkylthio-acety1ene)sThe thermal properties of poly(bis-alkylthio-acetylene)s in the temperature range from 30 "C to 600 "C have been investigated. On the basis of thermal analysis, "C-solid state NMR and ESR spectroscopic measurements on the solid phases and gas chromatographic ChardCteriTdtiOn of the volatile pyrolysis products, possible pyrolysis reactions are formulated. A simple kinetic model of the thermal behaviour of poly(bis-methylthio-acetylene) in a wide range of temperature and time is suggested.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.