The impact of Li doping on the temperature-induced phase transitions in silver niobates Ag1–x Li x NbO3 has been investigated using a combination of high-resolution powder neutron diffraction and synchrotron X-ray diffraction. Considering both the cell metric and distortions of the NbO6 octahedra, estimated by Rietveld refinements, it is shown that the sequence of temperature-induced phases in AgNbO3 is P21 am → Pcam → Cmcm → P4/mbm → Pm3̅m. This sequence is simpler than that proposed in earlier studies. Evidence is presented for a second-order Jahn–Teller distortion in the Pcam phase. At x > 0.05, Li doping favors the formation of a rhombohedral phase in space group R3c, and such samples display the temperature-induced sequence R3c → Pbnm → Cmcm → P4/mbm → Pm3̅m. Unusual volume changes associated with the phase transitions point to the potential importance of lattice matching in optimizing the properties of thin films of doped AgNbO3.

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